[95] T. Canstanheiro,* T. Besset,* J. Fluo. Chem. 2024, 110296.
DOI: 10.1016/j.jfluchem.2024.110296

Regioselective Difunctionalization of Alkenes with CF2FG Moieties

[94] F. Buttard, M. Daghmoum, M. Arribat, M.-Y. Chen, P. Retailleau, T. Besset,* X. Guinchard,*
Adv. Synth. Catal. 2024, DOI: 10.1002/adsc.202400411.
Synthesis of Fluorinated Spiroindolenines by Transition Metal-Catalyzed Indole Dearomatizations

[93] Dorian Dupommier, Martin Vuagnat, Javid Rzayev, Sourav Roy, P. Jubault, T. Besset,*
Angew. Chem. Int. Ed. 2024, e202403950 ; DOI: 10.1002/anie.202403950
Site-Selective Ortho/Ipso C-H Difunctionalizations of Arenes using Thianthrene as a Leaving Group

[92] J. Fichez, M. I. Lapuh, F. Buttard, T. Besset,*
Adv. Synth. Catal. 2024, DOI: 10.1002/adsc.202400316
Selectivity Switch in Non-Directed Palladium-Catalyzed C-H Olefination of Chlorobenzene Derivatives

[91] A.-C. Gaumont,* P. Jubault,* T. Besset,
Eur. J. Org. Chem. DOI : 10.1002/ejoc.202400193
LabEx SynOrg: Research Institute Dedicated to Molecular Chemistry

[90] C. Zhao, T. Besset, P. Jubault,*
Adv. Synth. Catal. 2024, DOI : 10.1002/adsc.202400146
Ruthenium(II)-Catalyzed Enantioselective Synthesis of 1,2-trans-Disubstituted PhSO2CF2-containing Cyclopropanes

[89] M. Vuagnat, P. Jubault, T. Besset,*
Chem. Commun. 2024, 60, 2244, DOI : 10.1039/D3CC05919G
Sequential ortho-/meta-C–H functionalizations of N-tosyl-benzamides for the synthesis of polyfunctionalized arenes

[88] F. Buttard, J. Vigier, H. Lebel,* T. Besset,*
Eur. J. Org. Chem. 2024, 27, e202301205, DOI : 10.1002/ejoc.202301205
C-Centered Radical Intermediates for C(sp3)H Bonds Functionalization: An Emerging Approach towards Alkyl Thiocyanates

[87] J. Vigier, M. Gao, P. Jubault, H. Lebel,* T. Besset,*
Chem. Commun. 2024, DOI: 10.1039/D3CC04624A.
Divergent process for the catalytic decarboxylative thiocyanation and isothiocyanation of carboxylic acids promoted by visible light.


[86] E. Nobile, F. Doche, T. Castanheiro, D. G. Musaev,* T. Besset,*
Chem. Eur. J. 2023, e202303362. DOI: 10.1002/chem.202303362.
Copper-Catalyzed CH (Phenylsulfonyl)Difluoromethylation of Acrylamides: Scope, Mechanism, and Critical Role of Additives”

[85] C. Huang, T. Besset, C. Legault, P. Jubault,
Chem. Eur. J. 2023, DOI: e202303070.
Experimental and Computational Studies for the Synthesisof Functionalized Cyclopropanes from α-Substituted AllylicDerivatives with Ethyl Diazoacetate

[84] F. Doche, T. Poisson, T. Besset,*
ACS Catal. 2023, 13, 14112. DOI: 10.1021/acscatal.3c03249.
Photocatalytic α-Trifluoromethylthiolation of N-Acyl Amines

[83] X. Huang, T. Besset, P. Jubault, S. Couve-Bonnaire,*
Adv. Synth. Catal. 2023, 365, 2467. DOI: 10.1002/adsc.202300565.
Fluorinated substrates as Michael acceptors towards fine chemicals.”

[82] L. Monsigny, F. Doche, T. Besset,* Beilstein J.
Org. Chem. 2023, 19, 448. DOI: 10.3762/bjoc.19.35
Transition-metal-catalyzed CH bond activation as a sustainable strategy for the synthesis of fluorinated molecules: an overview.”

[81] F. Buttard*, T. Besset,*
SynOpen 2023, 07, 117. DOI: 10.1055/a-2041-0188.
Emergent Strategies for Catalytic Enantioselective DirectThiocyanation and Selenocyanation reactions.”


[80] F. Doche, J. Esudero, F. Petit-Cancelier, H.-Y. Xiong, S. Couve-Bonnaire, D. Audisio, T. Poisson, T. Besset,*
Chem. Eur. J. 2022, DOI: 10.1002/chem.202202099.
Directed Palladium Catalyzed CH (Ethoxycarbonyl)difluoromethylthiolation Reactions.”

[79] M. Vuagnat, V. Tognetti, P. Jubault, T. Besset,*
Chem. Eur. J. 2022, DOI: 10.1002/chem.202201928.
Ru(II)-Catalyzed Hydroarylation of in situ generated 3,3,3-Trifluoro-1-propyne by CH Bond Activation: A Facile and Practical Access to β-trifluoromethylstyrenes”

[78] E. Nobile, J.-P. Hébert, T. Castanheiro, A. Ledoux, T. Besset,*
Org. Process Res. Dev. 2022, DOI: 10.1021/acs.oprd.2c00099.
Cost-efficient, Multigram Scalable Synthesis of Shelf-Stable Electrophilic (Phenylsulfonyl)difluoromethylating Reagents

[77] X. Huang, T. Besset, P. Jubault, S. Couve-Bonnaire,
J. Org. Chem. 2022, 87, 9210. DOI: 10.1021/acs.joc.2c00937.
Phospha-Michael addition on α-fluorinated acrylates: a straightforward access to polyfunctionalized fine chemicals

[76] F. Petit-Cancelier, L. Ruyet, S. Couve-Bonnaire, T. Besset,*
Adv. Synth. Catal. 2022, 364, 1498-1502. DOI: 10.1002/adsc.202200059.
Distal Construction of a Carbon-SCF2R Bond on Aliphatic Alcohols Enabled by 1,5-Hydrogen-Atom Transfer

[75] J. Fichez, D. Dupommier, T. Besset,*
Synthesis, 2022, accepté.
“Direct Synthesis of Disubstituted Trifluoromethylthiolated Alkenes”(Review)
Invited contribution for the Synthesis Special Issue honoring Prof. Ferenc Fülöp

[74] M. Gao, M. Vuagnat, P. Jubault, T. Besset*
Eur. J. Org. Chem. 2022, e202101255. DOI: 10.1002/ejoc.202101255. Very Important Paper
N-Thiocyanato-2,10-camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents
Invited contribution for the Eur. J. Org. Chem. Special Issue honoring Prof. Ferenc Fülöp.


[73] E. Nobile, T. Castanheiro, T. Besset,*
Chem. Commun. 2021, 57, 12337. DOI: 10.1039/d1cc04737j
CH Electrophilic (phenylsulfonyl)difluoromethylation of (hetero)arenes with a newly designed reagent”

[72] F. Petit-Cancelier, S. Couve-Bonnaire, T. Besset,*
Tetrahedron 2021, 98, 132446. DOI: 10.1016/j.tet.2021.132446
Synthesis of a Library of SCF2CO2Et Reagents: An Access To Original (Ethoxycarbonyl)difluoromethylthioesters
Invitation for a special Issue in Tetrahedron entitled “Fluorine and Chalcogens”

[71] L. Ruyet, T. Poisson, T. Besset,*
Eur. J. Org. Chem. 2021, 3407. DOI: 10.1002/ejoc.202100580
Transition Metal-Free Regioselective Remote CH Bond 2,2,2-Trifluoroethoxylation of 8-Aminoquinoline Derivatives at the C5 Position”

[70] L. Ruyet, M. I. Lapuh, V. S. Koshti, T. Földesi, P. Jubault, T. Poisson, Z. Novák, T. Besset,*
Chem. Commun. 2021, 57, 6241. DOI: 10.1039/d1cc02007b
Z-Selective Pd-catalyzed 2,2,2-trifluoroethylation of acrylamides at room temperature
Invitation for a special Theme Collection “Functionalization of unreactive C-H bonds”
Highlight dans En direct des laboratoires

[69] T. Charvillat, P. Bernardelli, M. Daumas, X. Pannecoucke, V. Ferey, T. Besset,*
Chem. Soc. Rev. 2021, 50, 8178. DOI: 10.1039/d0cs00736f
Hydrogenation of fluorinated molecules: an overview” (Review)

[68] M. Gao, M. Vuagnat, M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset,*
Chem. Eur. J. 2021, 27, 6145. DOI: 10.1002/chem.202004974

Design and Use of Electrophilic Thiocyanating and Selenocyanating Reagents: a New Trend for the Construction of SCN- and SeCN-containing Compounds” (Review)
This article also appears in Reviews Showcase


[67] X. Huang, E. David, P. Jubault, T. Besset, S. Couve-Bonnaire,*
J. Org. Chem. 2020, 85, 14055. DOI: 10.1021/acs.joc.0c02081.
Organocatalyzed Sulfa-Michael Addition of Thiophenols on Trisubstituted -Fluoroacrylates, a Straightforward Access to Chiral Fluorinated Compounds

[66] S. Mazeh, I. Lapuh, T. Besset*
CHIMIA 2020, 74, 871. DOI: 10.2533/chimia.2020.871.
Advances in the Synthesis of Fluorinated Scaffolds by Transition Metal-Catalyzed CH Bond Activation(Review)
Invitation for a special issue on ’Innovative Tools in Organic Chemistry’

[65) I. Lapuh, S. Mazeh, T. Besset*
ACS Catal. 2020, 10, 12898. DOI: 10.1021/acscatal.0c03317.
Chiral Transient Directing Groups in Transition-Metal-Catalyzed Enantioselective CH Bond Functionalization(Review)

[64] M. Gao, M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset,
Chem. Eur. J. 2020, DOI: 10.1002/chem.202003521.
Pd‐Catalyzed Directed Thiocyanation Reaction by C—H Bond Activation
Part of a Special Issue celebrating the 1000th Issue of Chemistry—A European Journal.
This article also appears in: Hot Topic: C-H Activation, XXII International Symposium on Homogeneous Catalysis
The Chemistry institute of CNRS spoked of this article (press release by CNRS).

[63] E. Nobile, T. Castanheiro, T. Besset
Angew. Chem. Int. Ed. 2021,60, 12170. DOI: 10.1002/ange.202009995.
Radical‐Promoted Distal CH Functionalization of C(sp3) Centers with Fluorinated Moieties (Review)

[62] M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset
Org. Lett. 2020, 22, 7556. DOI: 10.1021/acs.orglett.0c02750.
Pd-Catalyzed Selective Chlorination of Acrylamides at Room Temperature

[61] L. Ruyet, T. Besset*
Beilstein J.
Org. Chem. 2020, 16, 1051. DOI:10.3762/bjoc.16.92.
Copper-based fluorinated reagents for the construction of CF2R-containing molecules (R ≠ F). (Review)
Invited contribution for the “Copper-Catalyzed Reactions for Organic Synthesis” thematic issue of the Beilstein Journal of Organic Chemistry

[60] M. Barday, R. Blieck, L. Ruyet, T. Besset*
Tetrahedron 2020, 76, 131153. DOI: 10.1016/j.tet.2020.131153.
Remote trifluoromethylthiolation of alcohols under visible light.
Invited contribution for the special issue for Nuno Maulide’s Young Investigator Award.

[59] K. Balanna, K. Madica, S. Mukherjee, A. Ghosh, T. Poisson, T. Besset, G. Jindal, A.T. Biju,
Chem. Eur. J. 2020, 26, 818. DOI: 10.1002/chem.201905177.
N-Heterocyclic Carbene-Catalyzed Formal [6+2] Annulation Reaction via Cross- Conjugated Aza-Trienolate Intermediates.

[58] F. Petit-Cancelier, B. François, X. Pannecoucke, S. Couve-Bonnaire, T. Besset*
Adv. Synth. Catal. 2020, 362, 760. DOI:10.1002/adsc.201901454
S-(Diethyl phosphonodifluoromethyl)Benzenesulfonothioate: A New Reagent for the Synthesis of SCF2PO(OEt)2-containing Molecules.


[57] M.-Y. Chen, X. Pannecoucke, P. Jubault, T. Besset,*
J. Org. Chem. 2019, 84, 13194. DOI: 10.1021/acs.joc.9b01872
Access to Isothiazolones from Simple Acrylamides by Pd-Catalyzed CH Bond   ActivationInvited contribution for the special issue on C-H Bond Functionalization.

[56] J. Wang, H.-Y. Xiong, E. Petit, L. Bailly, X. Pannecoucke, T. Poisson, T. Besset,*
Chem. Commun. 2019, 55, 8784. DOI: 10.1039/C9CC01851D
BiCl3-Mediated Direct Functionalization of Unsaturated CC Bonds with an Electrophilic SCF2PO(OEt)2 Reagent – Contribution to the Emerging Investigators Issue 2019

[55] E. Carbonnel, T. Poisson, P. Jubault, X. Pannecoucke, T. Besset,*
Front. Chem. 2019
, 7, 111. DOI: 10.3389/fchem.2019.

Recent Advances for the Direct Introduction of the CF2Me Moiety.

[54] X. Pannecoucke, T. Besset*
Org. Biomol. Chem. 2019, 1683. DOI:10.1039/C8OB02995D
Use of ArSO2SRf Reagents: An Efficient Tool for the Introduction of SRf Moieties. (Review – Invited contribution for Organic & Biomolecular Chemistry New Talent themed issue)


[53] T. Besset,* G. McGlacken,* M. Schnuerch,*
Eur. J. Org. Chem. 2018, 6032.
European Research in Focus: CH Activation in Organic Synthesis (CHAOS). (Guest editorial)

[52] A Bouchard, V. Kairouz, M. Manneveau, H.-Y. Xiong, T. Besset,* X. Pannecoucke, H. Lebel,*
J. Flow Chem. 2018, DOI: 10.1007/s41981-018-0023-4.
Continuous flow palladium-catalyzed trifluoromethylthiolation of CH bonds.

[51] S. Mukherjee, S. Shee, T. Poisson, T. Besset, A. T. Biju,*
Org. Lett. 2018, 20, 6998.
Enantioselective N-Heterocyclic Carbene-Catalyzed Cascade Reaction for theSynthesis of Pyrroloquinolines via N-H Functionalization of Indoles.

[50] Q. Zhao, M.-Y. Chen, T. Poisson, X. Pannecoucke, J.-P. Bouillon, T. Besset
Eur. J. Org. Chem. 2018, 6167. DOI: 10.1002/ejoc.201801071
Pd‐Catalyzed Trifluoromethylthiolation of Unsaturated Compounds: A General Approach

[49] Q. Zhao, J. Wang, T. Besset, X. Pannecoucke, J.-P. Bouillon, T. Poisson
Tetrahedron 2018, 74, 6033
Palladium-catalyzed synthesis of 3-trifluoromethylated 1,3-dienes from acrylate derivatives and BTP

[48] C. Sambiagio, D. Schönbauer, R. Blieck, T. Dao-Huy, G. Pototschnig, P. Schaaf, T. Wiesinger, M. F. Zia, J. Wencel-Delord, T. Besset, B. U. W. Maes, M. Schnürch
Chem. Soc. Rev. 2018, 47, 6603
A comprehensive overview of directing groups applied in metal catalysed CH functionalisation chemistry

[47] F. Gelat, A. Patra, X. Pannecoucke, A.T. Biju, T. Poisson, T. Besset
Org. Lett. 2018, 20, 3897
N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters
Highlighted in Chemistry Views

[46] F. Gelat, T. Poisson, X. Pannecoucke, A. T. Biju, T. Besset
Eur. J. Org. Chem. 2018, 3693. DOI : 10.1002/ejoc.201800418. Selected as Very Important Paper
Trifluoromethylthiolation of α-Chloroaldehydes: Access to Quaternary SCF3-Containing Centers

[45] E. Carbonnel, X. Pannecoucke, T. Besset, P. Jubault, T. Poisson
Chem Commun. 2018, 54, 2491
An Electrophilic Reagent for the Synthesis of OCHFMe-Containing Molecules

[44] MA. Patra, F. Gelat, X. Pannecoucke, T. Poisson, T. Besset, A.T. Biju
Org. Lett. 2018, 20, 1086
Synthesis of 4-Difluoromethylquinolines by NHC-Catalyzed Umpolung of Imines

[43] M. V. Ivanova, T. Besset, X. Pannecoucke, T. Poisson
Synthesis. 2018, 50, 778
Palladium-Catalyzed Synthesis of Aryl and Heteroaryl difluoromethylated Phosphonates


[42] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson
Chem.Eur. J. 2017, 23,17318
Copper-Mediated Introduction of the CF2PO(OEt)2 Motif: Scope and Limitations

[41] Q. Zhao, T. Poisson, X. Pannecoucke, T. Besset
Synthesis. 2017,49, 4808
The Transient Directing Group Strategy: A New Trend in Transition-Metal-Catalyzed CH Bond Functionalization

[40] Q. Zhao, T. Poisson, X. Pannecoucke, J.P. Bouillon, T. Besset
Org.Lett. 2017, 19, 5106
Pd-Catalyzed Diastereoselective Trifluoromethylthiolation of Functionalized Acrylamides

[39] E. Carbonnel, T. Besset, T. Poisson, D. Labar, X. Pannecoucke, P. Jubault
Chem Commun. 2017, 53, 5706
18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives

[38] Q. Zhao, V. Tognetti, L. Joubert, T. Besset, X. Pannecoucke, J.-P. Bouillon, T. Poisson
Org. Lett. 2017, 19, 2106
Palladium-Catalyzed Synthesis of 3-Trifluoromethyl Substituted 1,3-Butadienes by Means of Directed CH Bond Functionalization

[37] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke,T. Poisson
Eur. J. Org. Chem. 2017, 2475
Copper Mediated (Diethyl phosphono)difluoromethylthiolation of α-Bromo-Ketones


[36] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson
Angew.Chem. Int. Ed. 2016, 55, 14141
Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2 with α-Diazocarbonyl Derivatives

[35] H.-Y. Xiong, X. Pannecoucke, T. Besset*
Angew. Chem. Int. Ed. 2016, 55, 13490
Press release by CNRS
A New Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group onto Molecules

[34] H.-Y. Xiong, X. Pannecoucke, T. Besset,*
Chem. Eur. J. 2016, 22, 16734
Recent Advances in the Synthesis of SCF2H- and SCF2FG-containing Molecules

[33] H.-Y. Xiong, D. Cahard, X. Pannecoucke, T. Besset*
Eur. J. Org. Chem. 2016, 3625
Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)H Bonds at Room Temperature

[32] T. Besset, P. Jubault, X. Pannecoucke, T. Poisson*
Org. Chem. Front. 2016, 3, 1004
New Entries Toward the Synthesis of OCF3-Containing Molecules

[31] M. V. Ivanova, A. Bayle, T. Besset, X. Pannecoucke, T. Poisson*
Chem. Eur. J. 2016, 22, 10284
New Prospects Toward the Synthesis of Difluomethylated Phosphate Mimics

[30] H.-Y. Xiong, X. Pannecoucke, T. Besset*
Org. Chem. Front. 2016, 3, 620
Oxidative Trifluoromethylthiolation and Thiocyanation of Amines: a General Approach to NS Bond Formation

[29] Q. Zhao, T. Besset, T. Poisson, J.-P. Bouillon,*X. Pannecoucke
Eur. J. Org. Chem. 2016, 76
Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed CH Bond Functionalization


[28] M. I. Ivanova, A. Bayle, T. Besset, T. Poisson, *X. Pannecoucke
Angew. Chem. Int. Ed. 2015, 54, 13406
Copper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A Mild and General Approach to Fluorinated Phosphate Mimics

[27] T. Besset,* T. Poisson,* X. Pannecoucke
J. Fluorine Chem. 2015, 178, 225
1,4-Addition of the CF3 group, perfluoroalkyl groups and functionalized difluoromethylated moieties: An overview

[26] M.-C. Belhomme, T. Besset, T. Poisson,* X. Pannecoucke
Chem. Eur. J. 2015, 21, 12836
Recent Progress Toward the Introduction of Functionalized Difluoromethylated building blocks

[25] H.-Y. Xiong, T. Besset,* D. Cahard, X. Pannecoucke
J. Org. Chem. 2015, 80, 4204
Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)-H Bonds

[24] T. Besset,* T. Poisson,* X. Pannecoucke
Eur. J. Org. Chem. 2015, 2765
Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes


[23] T. Besset,* T. Poisson,* X. Pannecoucke
Chem. Eur. J. 2014, 20, 16830
Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C H Bond Functionalization

[22] T. Besset,* T. Poisson,* X. Pannecoucke
Eur. J. Org. Chem. 2014, 7220
Access to Difluoromethylated Alkynes through the Castro-Stephens Reaction

[21] T. Besset,* D. Cahard,* X. Pannecoucke
J. Org. Chem. 2014, 79, 413
Regio- and Diastereoselective Direct Cu-Mediated Trifluoromethylation of Functionalized Alkenes

[20] M.-C. Belhomme, D. Dru, H.-Y. Xiong, D. Cahard, T. Besset,* T. Poisson,* X. Pannecoucke
Synthesis 2014, 1859
Copper Mediated Direct Functionalization of Unsaturated C–C Bonds using BrCF2CO2Et: a Straightforward Access to Highly Valuable Difluoroacetylated Alkenes.” (Special Topic Issue on “Copper Chemistry” ed. Prof. E. M. Carreira)

[19] V. Bizet, T. Besset, J. A. Ma, D. Cahard*
Curr. Top. Med. Chem. 2014, 14, 901
Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions

[18] C. S. Fuchs, M. Hollauf, M. Meissner, R. C. Simon, T. Besset
J. N. H. Reek, W. Riethorst, F. Zepeck, W. Kroutil*
Adv. Synth. Cat. 2014, 356, 2257
Dynamic Kinetic Resolution of 2-Phenylpropanal Derivatives to Yield β-Chiral Primary Amines via Bioamination


[17] T. Ferrary, E. David, G. Milanole, T. Besset, P. Jubault,* X. Pannecouke
Org. Lett. 2013, 15, 5598
A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael Initiated Ring Closure reaction

[16] T. Besset,* R. Gramage-Doria, J. N. H. Reek*
Angew. Chem. Int. Ed. 2013, 52, 8795
Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes

[15] T. Besset, R. Gramage-Doria, J. N. H. Reek*
Curr. Org. Chem. 2013, 17, 1489
Transition-Metal Encapsulation within Supramolecular Diphosphine Capsules.” Special issue on “Nanoreactors and molecular prisons

[14] D. Anselmo, R. Gramage-Doria, T. Besset, M. V. Escárcega-Bobadilla, G. Salassa, E. C. Escudero-Adán,
M. Martínez Belmonte, E. Martin,J. N. H. Reek,* A. W. Kleij*
Dalton Trans. 2013, 42, 7595
Supramolecular Bulky Phosphines Comprising of 1,3,5-Triaza-7-phosphaadamantane and Zn(salphen)s: Structural Features and Application in Hydrosilylation Catalysis

[13] T. Besset, D. W. Norman, J. N. H. Reek
Adv. Synth. Catal. 2013, 355, 348
Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature

[12] F. W. Patureau, T. Besset, F. Glorius,* checked by T. Harada, T. Fukuyama
Org. Synth. 2013, 90, 41
Preparation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation


[11] T. Besset, C. Schneider, D. Cahard*
Angew. Chem. Int. Ed. 2012, 51, 5048
Tamed (Hetero)Arene Trifluoromethylation

[10] F. W. Patureau, T. Besset, R. Fröhlich, F. Glorius*
C. R. Chim. 2012, 15, 1081

On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings; De la sélectivité dans des réactions d’hétéro-couplage par C-H activation catalysées au Rh(III)

[9] N. Schroder, T. Besset, F. Glorius*
Adv. Synth. Catal. 2012, 354, 579

Synthesis of Olefin-Oxazoline-Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination


[8] T. Besset, N. Kuhl, F. W. Patureau, F. Glorius*
Chem. Eur. J. 2011, 17, 7167
Rh(III)-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated -Amino Acid Derivatives and other Linear 1,3-Butadienes

[7] T. Besset, E. Braud,* C. Garbay, S. Kolb, P.-M. Léo, C. Morin*
Eurjchem 2011, 2, 433
Preparation and evaluation of a set of bis-(methoxycarbonyl-methylthio)-heteroquinones as CDC25B phosphatase inhibitors

[6] S. Rakshit, C. Grohmann, T. Besset, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2350
Rh[III]-catalyzed directed C-H olefination using an internal oxidant: mild, efficient and versatile

[5] F. W. Patureau, T. Besset, N. Kuhl, F. Glorius*
J. Am. Chem. Soc. 2011, 133, 2154
Diverse strategies towards indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes

[4] F. W. Patureau, T. Besset, F. Glorius*
Angew. Chem. Int. Ed. 2011, 50, 1064
Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides


[3] T. Besset, C. Morin*
Synthesis 2009, 1753
Synthesis of 3,6-Dimethoxybenzene-1,2-diamine and of 4,7-Dimethoxy-2-methyl-1H-benzimidazole


[2] C. Morin, T. Besset, J.-C. Moutet, M. Fayolle, M. Brueckner, D. Limosin, K. Becker, E. Davioud-Charvet*
Org. Biomol. Chem. 2008, 6, 2731
The aza-analogues of 1,4-naphthoquinones are potent substrates and inhibitors of plasmodial thioredoxin and glutathione reductases and of human erythrocyte glutathione reductase


[1] I. Abrunhosa-Thomas, O. Roy, M. Barra, T. Besset, P. Chalard,* Y. Troin*
Synlett 2007, 1613
Diastereoselective synthesis of 2-monosubstituted and 2,6-disubstituted piperidines